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Multiple Choice
Which of the following structures represents a zwitterion?
A
H$_3$N$^+$–CH$_2$–COO$^-$
B
H$_2$N–CH$_2$–COOH
C
H$_2$N–CH$_2$–COO$^-$
D
H$_3$N$^+$–CH$_2$–COOH
Verified step by step guidance
1
Step 1: Understand the concept of a zwitterion. A zwitterion is a molecule that contains both a positive and a negative charge, but is overall electrically neutral. This typically occurs in amino acids at a specific pH (isoelectric point).
Step 2: Analyze the given structures. Look for the presence of both a positively charged group (e.g., H$_3$N$^+$) and a negatively charged group (e.g., COO$^-$) within the same molecule.
Step 3: Evaluate the first structure, H$_3$N$^+$–CH$_2$–COO$^-$. This structure contains a positively charged amino group (H$_3$N$^+$) and a negatively charged carboxylate group (COO$^-$), making it a zwitterion.
Step 4: Evaluate the second structure, H$_2$N–CH$_2$–COOH. This structure has a neutral amino group (H$_2$N) and a neutral carboxylic acid group (COOH), so it is not a zwitterion.
Step 5: Evaluate the remaining structures. H$_2$N–CH$_2$–COO$^-$ has a neutral amino group and a negatively charged carboxylate group, while H$_3$N$^+$–CH$_2$–COOH has a positively charged amino group and a neutral carboxylic acid group. Neither of these are zwitterions because they lack both charges simultaneously.