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Multiple Choice
Which of the following is the correct Lewis dot structure for the neutral compound Cl2O2, given that the arrangement of atoms is Cl–O–O–Cl?
A
Each Cl atom is bonded to an O atom, but the O atoms are not bonded to each other; each O atom has three lone pairs.
B
Each Cl atom is bonded to an O atom, the two O atoms are bonded to each other, and each O atom has two lone pairs; each Cl atom has three lone pairs.
C
Each Cl atom is bonded directly to the other Cl atom, and each O atom is bonded to both Cl atoms; each O atom has three lone pairs.
D
Each Cl atom is bonded to both O atoms, forming a ring structure; each O atom has two lone pairs.
Verified step by step guidance
1
Step 1: Identify the molecular formula and the given atomic arrangement. The compound is Cl2O2, and the atoms are arranged as Cl–O–O–Cl, meaning each chlorine atom is bonded to an oxygen atom, and the two oxygen atoms are bonded to each other.
Step 2: Determine the total number of valence electrons available. Chlorine (Cl) has 7 valence electrons, and oxygen (O) has 6 valence electrons. Calculate the total valence electrons for Cl2O2 by summing 2 × 7 (for Cl) and 2 × 6 (for O).
Step 3: Draw the skeletal structure based on the given arrangement: Cl bonded to O, O bonded to O, and O bonded to Cl. Place single bonds between these atoms initially, remembering that each bond represents 2 electrons.
Step 4: Distribute the remaining valence electrons as lone pairs to satisfy the octet rule for each atom. Start by completing the octets of the more electronegative atoms (oxygen), then assign lone pairs to chlorine atoms. Remember that each oxygen atom should have two lone pairs if bonded to two atoms, and chlorine atoms typically have three lone pairs when bonded to one atom.
Step 5: Verify the Lewis structure by counting all electrons (bonding and lone pairs) to ensure the total matches the number of valence electrons calculated in Step 2, and confirm that each atom (except hydrogen, which is not present here) has a complete octet.