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Multiple Choice
After drawing the Lewis structure of SF6, what are the electron domain geometry and molecular geometry around the sulfur atom?
A
Electron domain geometry: trigonal bipyramidal; Molecular geometry: trigonal bipyramidal
B
Electron domain geometry: octahedral; Molecular geometry: octahedral
C
Electron domain geometry: tetrahedral; Molecular geometry: square planar
D
Electron domain geometry: octahedral; Molecular geometry: square pyramidal
Verified step by step guidance
1
Step 1: Draw the Lewis structure of SF6 by counting the total valence electrons. Sulfur (S) has 6 valence electrons, and each fluorine (F) has 7 valence electrons. Since there are 6 fluorines, total valence electrons = 6 (S) + 6 × 7 (F) = 48 electrons.
Step 2: Arrange the sulfur atom in the center and place six fluorine atoms around it. Connect each fluorine to sulfur with a single bond. Each bond accounts for 2 electrons, so 6 bonds use 12 electrons, leaving 36 electrons to be placed as lone pairs on the fluorines.
Step 3: Complete the octets of the fluorine atoms by placing three lone pairs (6 electrons) on each fluorine. This uses all remaining electrons and satisfies the octet rule for fluorine atoms.
Step 4: Determine the electron domain geometry by counting the regions of electron density around the sulfur atom. Since sulfur forms six single bonds and has no lone pairs, there are six electron domains, which corresponds to an octahedral electron domain geometry.
Step 5: Determine the molecular geometry by considering the positions of atoms only (ignoring lone pairs on the central atom). Since there are no lone pairs on sulfur, the molecular geometry is the same as the electron domain geometry, which is octahedral.