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Multiple Choice
Which of the following molecules is nonpolar but contains polar covalent bonds?
A
CHCl_3
B
H_2O
C
NH_3
D
CO_2
Verified step by step guidance
1
Step 1: Understand the difference between polar covalent bonds and molecular polarity. A polar covalent bond occurs when two atoms share electrons unequally due to differences in electronegativity, creating partial positive and negative charges within the bond.
Step 2: Recognize that molecular polarity depends on both the polarity of individual bonds and the geometry (shape) of the molecule. Even if a molecule has polar bonds, the overall molecule can be nonpolar if the bond dipoles cancel out due to symmetry.
Step 3: Analyze the molecular geometry of each molecule: CHCl_3 (trichloromethane) has a tetrahedral shape but with different atoms attached, leading to an overall polar molecule; H_2O (water) has a bent shape causing an overall polar molecule; NH_3 (ammonia) has a trigonal pyramidal shape, also polar.
Step 4: Examine CO_2 (carbon dioxide), which has two polar C=O bonds. However, CO_2 is linear and symmetrical, so the bond dipoles are equal in magnitude but opposite in direction, canceling each other out and making the molecule nonpolar overall.
Step 5: Conclude that CO_2 is the molecule that contains polar covalent bonds but is nonpolar as a whole due to its linear geometry and symmetrical distribution of bond dipoles.