Identify the atomic number of antimony (Sb), which is 51. This means Sb has 51 electrons to be placed in orbitals according to the Aufbau principle.
Recall the order of filling orbitals based on increasing energy levels: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, and so on.
Fill the orbitals with electrons following the order, making sure to respect the maximum number of electrons per orbital type: s (2), p (6), d (10). Continue until all 51 electrons are assigned.
After filling up to 4d^{10} (which accounts for 46 electrons), place the remaining 5 electrons in the 5p orbital, since it can hold up to 6 electrons.
Write the full electron configuration by combining all filled orbitals with their respective electron counts, ensuring the last part corresponds to 5p^{3} for antimony.