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Multiple Choice
Which type of salts will generally be more soluble in an acidic solution than in pure water?
A
Salts containing anions of weak acids, such as carbonates (CO_3^{2-}) and phosphates (PO_4^{3-})
B
Salts containing halide anions, such as Cl^- and Br^-
C
Salts containing nitrate anions (NO_3^-)
D
Salts containing alkali metal cations, such as Na^+ and K^+
Verified step by step guidance
1
Step 1: Understand that the solubility of salts in water can be influenced by the pH of the solution, especially if the salt contains anions that can react with H\textsuperscript{+} ions (protons) from an acid.
Step 2: Identify that salts containing anions of weak acids (like CO\_3\^{2-} from carbonic acid and PO\_4\^{3-} from phosphoric acid) can react with H\textsuperscript{+} ions in acidic solution, forming their corresponding weak acids and thus reducing the concentration of free anions.
Step 3: Recognize that this reaction shifts the dissolution equilibrium of the salt to dissolve more solid to replace the consumed anions, effectively increasing the salt's solubility in acidic solution compared to pure water.
Step 4: Contrast this with salts containing anions of strong acids (like NO\_3\^- from nitric acid) or halide ions (Cl\^-, Br\^-), which do not react significantly with H\textsuperscript{+} ions, so their solubility remains largely unchanged in acidic conditions.
Step 5: Conclude that salts containing anions of weak acids are generally more soluble in acidic solutions than in pure water due to the acid-base reaction that consumes the anions and drives dissolution.