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Multiple Choice
Which of the following is a correct Lewis dot structure for hydrogen cyanide (HCN)?
A
H–C=N with two lone pairs on nitrogen
B
H=C=N with one lone pair on nitrogen
C
H–C–N with three lone pairs on nitrogen
D
H–C≡N with a lone pair on nitrogen
Verified step by step guidance
1
Step 1: Determine the total number of valence electrons available for bonding in HCN. Hydrogen (H) has 1 valence electron, carbon (C) has 4, and nitrogen (N) has 5. Add these together to get the total valence electrons.
Step 2: Arrange the atoms in a reasonable skeletal structure. Since carbon is less electronegative than nitrogen and can form multiple bonds, place carbon between hydrogen and nitrogen: H–C–N.
Step 3: Use the total valence electrons to form bonds between atoms. Start by placing single bonds between H–C and C–N, then add multiple bonds as needed to satisfy the octet rule for carbon and nitrogen.
Step 4: Assign lone pairs to the atoms to complete their octets. Hydrogen only needs 2 electrons (a single bond), carbon needs 8 electrons total, and nitrogen also needs 8 electrons. Place lone pairs on nitrogen after bonding to complete its octet.
Step 5: Verify the Lewis structure by checking that the total number of electrons used (bonding and lone pairs) equals the total valence electrons calculated in Step 1, and that each atom (except hydrogen) satisfies the octet rule. The correct structure for HCN is H–C≡N with a lone pair on nitrogen.