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Multiple Choice
Which of the following Lewis structures best represents a polar molecule?
A
A bent molecule with two different atoms and lone pairs on the central atom, such as H_2O
B
A linear molecule with two identical atoms, such as O_2
C
A tetrahedral molecule with four identical atoms around the central atom, such as CH_4
D
A trigonal planar molecule with three identical atoms around the central atom, such as BF_3
Verified step by step guidance
1
Step 1: Understand that molecular polarity depends on both the polarity of individual bonds and the overall molecular geometry. A molecule is polar if it has polar bonds arranged asymmetrically, resulting in a net dipole moment.
Step 2: Analyze each molecular shape and its symmetry: linear molecules with identical atoms (like O_2) are nonpolar because the bond dipoles cancel out; tetrahedral molecules with four identical atoms (like CH_4) are also nonpolar due to symmetrical charge distribution; trigonal planar molecules with three identical atoms (like BF_3) are nonpolar because the dipoles cancel out in a symmetrical plane.
Step 3: Consider the bent molecule with two different atoms and lone pairs on the central atom (like H_2O). The presence of lone pairs creates an asymmetrical shape, and the different atoms create polar bonds that do not cancel out, resulting in a net dipole moment.
Step 4: Conclude that the bent molecule with lone pairs and different atoms is polar because its molecular geometry and bond polarity combine to produce an overall dipole moment.
Step 5: Therefore, the Lewis structure that best represents a polar molecule is the bent molecule with two different atoms and lone pairs on the central atom, such as H_2O.