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Multiple Choice
Which of the following molecules is polar?
A
CO_2
B
NH_3
C
CCl_4
D
BF_3
Verified step by step guidance
1
Step 1: Understand that molecular polarity depends on both the polarity of individual bonds and the geometry (shape) of the molecule, which affects how bond dipoles add up.
Step 2: Analyze the molecular geometry of each molecule using VSEPR theory: CO_2 is linear, NH_3 is trigonal pyramidal, CCl_4 is tetrahedral, and BF_3 is trigonal planar.
Step 3: Consider the electronegativity differences and bond dipoles: all these molecules have polar bonds due to differences in electronegativity between atoms (e.g., N-H, C=O, B-F, C-Cl).
Step 4: Determine if the molecular geometry allows the bond dipoles to cancel out: in CO_2 (linear) and BF_3 (trigonal planar), the bond dipoles are symmetrically arranged and cancel, making the molecules nonpolar; in CCl_4 (tetrahedral), the symmetrical arrangement also cancels dipoles.
Step 5: Recognize that NH_3 has a trigonal pyramidal shape with a lone pair on nitrogen, causing an asymmetrical distribution of charge and resulting in a net dipole moment, making NH_3 polar.