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Multiple Choice
Which of the following best describes the polarity of the molecule AsF_5?
A
AsF_5 is ionic.
B
AsF_5 is amphiprotic.
C
AsF_5 is a polar molecule.
D
AsF_5 is a nonpolar molecule.
Verified step by step guidance
1
Step 1: Identify the molecular geometry of AsF_5. Arsenic pentafluoride (AsF_5) has five fluorine atoms bonded to a central arsenic atom. The electron domain geometry for five bonding pairs is trigonal bipyramidal.
Step 2: Understand the symmetry of the molecule. In a trigonal bipyramidal geometry, the molecule is symmetrical with three fluorine atoms in the equatorial plane and two in the axial positions, arranged evenly around the central atom.
Step 3: Consider the polarity of individual bonds. Each As-F bond is polar because fluorine is more electronegative than arsenic, creating bond dipoles pointing from arsenic to fluorine.
Step 4: Analyze the vector sum of the bond dipoles. Due to the symmetrical trigonal bipyramidal shape, the bond dipoles cancel each other out, resulting in no net dipole moment for the molecule.
Step 5: Conclude the overall polarity. Since the bond dipoles cancel, AsF_5 is a nonpolar molecule despite having polar bonds. Therefore, the best description is that AsF_5 is nonpolar.