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Multiple Choice
Which of the following best describes the molecular polarity of SO_2?
A
SO_2 is a nonpolar molecule because it contains only nonpolar bonds.
B
SO_2 is a polar molecule because it has a symmetrical structure.
C
SO_2 is a nonpolar molecule because its shape is linear and the dipoles cancel out.
D
SO_2 is a polar molecule because it has a bent shape and an uneven distribution of electrons.
Verified step by step guidance
1
Identify the molecular geometry of SO\_2 by considering the Lewis structure. Sulfur (S) is the central atom bonded to two oxygen (O) atoms, and there is a lone pair of electrons on the sulfur atom.
Determine the shape of the molecule using VSEPR theory. With two bonded atoms and one lone pair on the central atom, the shape of SO\_2 is bent (angular), not linear.
Analyze the polarity of the bonds. The S–O bonds are polar because oxygen is more electronegative than sulfur, creating bond dipoles pointing towards the oxygen atoms.
Consider the molecular shape and how the bond dipoles combine. Because the molecule is bent, the bond dipoles do not cancel out, resulting in a net dipole moment.
Conclude that SO\_2 is a polar molecule due to its bent shape and uneven distribution of electron density, which leads to an overall molecular polarity.