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Multiple Choice
Which of the following solutions will form a precipitate when mixed with a solution of aqueous Na2CO3?
A
CaCl2(aq)
B
KNO3(aq)
C
NaCl(aq)
D
Li2SO4(aq)
Verified step by step guidance
1
Identify the ions present in the aqueous sodium carbonate (Na2CO3) solution. It dissociates into 2 Na\textsuperscript{+} ions and 1 CO\textsubscript{3}\textsuperscript{2-} ion.
For each given solution, write down the ions it dissociates into when dissolved in water: CaCl\textsubscript{2} \rightarrow Ca\textsuperscript{2+} and 2 Cl\textsuperscript{-}; KNO\textsubscript{3} \rightarrow K\textsuperscript{+} and NO\textsubscript{3}\textsuperscript{-}; NaCl \rightarrow Na\textsuperscript{+} and Cl\textsuperscript{-}; Li\textsubscript{2}SO\textsubscript{4} \rightarrow 2 Li\textsuperscript{+} and SO\textsubscript{4}\textsuperscript{2-}.
Consider the possible combinations of cations and anions from Na2CO3 and each salt to see if any insoluble compound (precipitate) can form. Use solubility rules to determine if a precipitate forms. For example, carbonate salts of Ca\textsuperscript{2+} are generally insoluble.
Check the solubility rules: most carbonates (CO\textsubscript{3}\textsuperscript{2-}) are insoluble except those of alkali metals (like Na\textsuperscript{+}, K\textsuperscript{+}, Li\textsuperscript{+}) and ammonium. Since CaCO\textsubscript{3} is insoluble, mixing CaCl\textsubscript{2} with Na2CO3 will form a precipitate of CaCO\textsubscript{3}.
Conclude that only the mixture of CaCl\textsubscript{2} and Na2CO3 will form a precipitate, while the others remain soluble due to the solubility of their respective ions with carbonate.