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Multiple Choice
Which of the following statements correctly describes the Lewis dot structure of carbon disulfide (CS_2)?
A
The central carbon atom forms a triple bond with one sulfur atom and a single bond with the other sulfur atom.
B
The central carbon atom forms two single bonds with two sulfur atoms, and carbon has two lone pairs.
C
The central carbon atom forms two single bonds with two sulfur atoms, and each sulfur atom has two lone pairs.
D
The central carbon atom forms two double bonds with two sulfur atoms, and all atoms have a complete octet.
Verified step by step guidance
1
Identify the central atom in the molecule CS_2, which is carbon because it is less electronegative than sulfur and can form multiple bonds.
Determine the total number of valence electrons available: Carbon has 4 valence electrons, and each sulfur has 6 valence electrons, so total valence electrons = 4 + 2 × 6 = 16.
Distribute electrons to form bonds between carbon and sulfur atoms. Start by placing single bonds between carbon and each sulfur, using 4 electrons (2 per bond).
Complete the octets of the sulfur atoms by adding lone pairs, then check if carbon has a complete octet. If carbon does not have 8 electrons, form double bonds by sharing lone pairs from sulfur with carbon.
Confirm that the final Lewis structure has carbon forming two double bonds with the two sulfur atoms, and that all atoms have a complete octet, which satisfies the octet rule for this molecule.