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Multiple Choice
Which of the following is the correct number of valence electrons for the neutral compound BrF, and which Lewis dot structure represents it?
A
BrF has 10 valence electrons; the Lewis structure shows Br with one lone pair and a triple bond to F, which has one lone pair.
B
BrF has 12 valence electrons; the Lewis structure shows Br with two lone pairs and a double bond to F, which has two lone pairs.
C
BrF has 14 valence electrons; the Lewis structure shows Br with three lone pairs and a single bond to F, which has three lone pairs.
D
BrF has 16 valence electrons; the Lewis structure shows Br with four lone pairs and a single bond to F, which has four lone pairs.
Verified step by step guidance
1
Determine the total number of valence electrons by adding the valence electrons of each atom in the molecule. Bromine (Br) is in group 17, so it has 7 valence electrons, and fluorine (F) is also in group 17 with 7 valence electrons. Therefore, total valence electrons = 7 (Br) + 7 (F) = 14.
Draw a skeletal structure with Br and F connected by a single bond. Each single bond represents 2 shared electrons, so subtract these from the total valence electrons: 14 - 2 = 12 electrons remaining to be placed as lone pairs.
Distribute the remaining 12 electrons as lone pairs to satisfy the octet rule for each atom. Start by placing lone pairs on the more electronegative atom (F) to complete its octet, then place the remaining electrons on Br.
Count the electrons around each atom to ensure both have a full octet (8 electrons). Br should have three lone pairs (6 electrons) plus the bonding pair (2 electrons), and F should have three lone pairs (6 electrons) plus the bonding pair (2 electrons).
Confirm that the total number of electrons used in the Lewis structure equals the total valence electrons calculated initially (14 electrons), and that the structure matches the description: Br with three lone pairs and a single bond to F, which also has three lone pairs.