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Multiple Choice
Which of the following ions, when combined with Ba^{2+}, forms a compound that is most soluble in water?
A
CO_3^{2-}
B
PO_4^{3-}
C
NO_3^-
D
SO_4^{2-}
Verified step by step guidance
1
Step 1: Understand that the solubility of ionic compounds in water depends on the solubility rules and the lattice energy of the compound formed between the cation and anion.
Step 2: Recall the common solubility rules: nitrates (NO_3^-) are generally soluble with all cations, while carbonates (CO_3^{2-}), phosphates (PO_4^{3-}), and sulfates (SO_4^{2-}) have varying solubilities depending on the cation.
Step 3: Consider the specific case of Ba^{2+} combined with each anion. BaCO_3 and Ba_3(PO_4)_2 are typically insoluble or sparingly soluble, BaSO_4 is known to be poorly soluble, and Ba(NO_3)_2 is highly soluble in water.
Step 4: Use the solubility product constant (K_{sp}) values if available to compare the solubility quantitatively. The higher the K_{sp}, the more soluble the compound is.
Step 5: Conclude that Ba^{2+} combined with NO_3^- forms Ba(NO_3)_2, which is the most soluble compound among the options given, based on solubility rules and K_{sp} data.