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Multiple Choice
Which of the following statements correctly describes the Lewis structure of ClBr3 (chlorine tribromide) as a neutral compound?
A
The central atom is bromine, surrounded by three single bonds to chlorine atoms and no lone pairs.
B
The central atom is chlorine, surrounded by three double bonds to bromine atoms and one lone pair on chlorine.
C
The central atom is chlorine, surrounded by three single bonds to bromine atoms and two lone pairs on chlorine.
D
The central atom is bromine, surrounded by three single bonds to chlorine atoms and three lone pairs on bromine.
Verified step by step guidance
1
Identify the total number of valence electrons in ClBr3 by adding the valence electrons of chlorine and bromine atoms. Chlorine has 7 valence electrons, and bromine also has 7 valence electrons each.
Determine the central atom by considering electronegativity and the number of atoms. Typically, the less electronegative atom or the atom that can form more bonds is the central atom. Here, chlorine is less electronegative than bromine, so chlorine is likely the central atom.
Draw single bonds between the central chlorine atom and each of the three bromine atoms. Each single bond represents 2 electrons shared between atoms.
Distribute the remaining valence electrons as lone pairs to satisfy the octet rule for each atom. Start by completing the octets of the outer bromine atoms, then place any leftover electrons as lone pairs on the central chlorine atom.
Count the lone pairs on the central chlorine atom after bonding. For ClBr3, chlorine will have two lone pairs, and each bromine will have three lone pairs, resulting in a total of 28 valence electrons accounted for and a neutral molecule.