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Multiple Choice
Which of the following statements correctly describes the Lewis dot structure of neutral SeO_2?
A
Selenium is the central atom, bonded to two oxygen atoms, with no lone pairs on selenium and each oxygen atom having three lone pairs.
B
Selenium is bonded to one oxygen atom and has three lone pairs, while the oxygen atom has one lone pair.
C
Selenium is the central atom, bonded to two oxygen atoms, with two lone pairs on selenium and each oxygen atom having one lone pair.
D
Selenium is the central atom, bonded to two oxygen atoms, with one lone pair on selenium and each oxygen atom having two lone pairs.
Verified step by step guidance
1
Step 1: Determine the total number of valence electrons available for SeO_2. Selenium (Se) is in group 16 and has 6 valence electrons, and each oxygen (O) atom also has 6 valence electrons. Since there are two oxygen atoms, total valence electrons = 6 (Se) + 2 × 6 (O) = 18 electrons.
Step 2: Identify the central atom. Selenium is less electronegative than oxygen, so selenium will be the central atom bonded to two oxygen atoms.
Step 3: Draw single bonds between selenium and each oxygen atom. Each single bond uses 2 electrons, so 2 bonds use 4 electrons. Subtract these from the total valence electrons: 18 - 4 = 14 electrons remaining.
Step 4: Distribute the remaining electrons as lone pairs to satisfy the octet rule. Start by placing lone pairs on the oxygen atoms to complete their octets. Each oxygen needs 6 more electrons (3 lone pairs) to complete an octet after the single bond. Assign these lone pairs to oxygens first.
Step 5: Check the selenium atom's electrons after assigning lone pairs to oxygens. Selenium will have some lone pairs left. Adjust bonding if necessary (e.g., form double bonds) to ensure all atoms have complete octets and the total number of electrons equals 18. This leads to selenium having one lone pair and each oxygen having two lone pairs, matching the correct Lewis structure.