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Multiple Choice
Which of the following compounds is least soluble in water?
A
AgCl
B
K_2SO_4
C
NH_4Br
D
NaNO_3
Verified step by step guidance
1
Step 1: Understand that solubility in water depends on the compound's ability to dissociate into ions and interact with water molecules. Ionic compounds that form ions which strongly interact with water tend to be more soluble.
Step 2: Recall the general solubility rules for ionic compounds in water: most alkali metal salts (like Na+ and K+) and ammonium salts (NH_4^+) are soluble, as well as most nitrates (NO_3^-).
Step 3: Analyze each compound: K_2SO_4 contains K+ and SO_4^{2-}, both generally soluble; NH_4Br contains NH_4^+ and Br^-, both soluble; NaNO_3 contains Na+ and NO_3^-, both soluble; AgCl contains Ag^+ and Cl^-, and silver halides are known to be poorly soluble.
Step 4: Use the solubility product constant (K_{sp}) concept: compounds with very low K_{sp} values are less soluble. AgCl has a very low K_{sp}, indicating low solubility in water.
Step 5: Conclude that among the given compounds, AgCl is the least soluble in water due to its low solubility product and the nature of silver halides.