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Multiple Choice
What is the standard enthalpy of formation (ΔH_f^ext{°}) value for CO_2(g) in kJ/mol?
A
0 kJ/mol
B
-110.5 kJ/mol
C
-393.5 kJ/mol
D
+393.5 kJ/mol
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Verified step by step guidance
1
Understand that the standard enthalpy of formation (\( \Delta H_f^{\circ} \)) of a compound is defined as the enthalpy change when one mole of the compound is formed from its elements in their standard states under standard conditions (usually 1 atm and 25°C).
Recognize that for carbon dioxide gas (\( \text{CO}_2(g) \)), the formation reaction from its elements in their standard states is: \(\n\)\(\n\)\( \text{C (graphite)} + \text{O}_2(g) \rightarrow \text{CO}_2(g) \)
Recall that the standard enthalpy of formation of an element in its standard state (like graphite for carbon or \( \text{O}_2 \) gas for oxygen) is defined as zero. This is why the enthalpy of formation for \( \text{CO}_2(g) \) is not zero.
Use standard thermodynamic tables or reliable data sources to find the value of \( \Delta H_f^{\circ} \) for \( \text{CO}_2(g) \), which is typically given in kJ/mol.
Interpret the sign and magnitude of the value: a negative value indicates that the formation of \( \text{CO}_2(g) \) from its elements releases energy (exothermic process), which is consistent with combustion reactions.