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Multiple Choice
Which of the following best describes the Lewis dot structure for the neutral compound CCl4?
A
A central carbon atom single-bonded to four chlorine atoms, with each chlorine atom having three lone pairs.
B
A central carbon atom single-bonded to four chlorine atoms, with each chlorine atom having two lone pairs.
C
A central carbon atom double-bonded to two chlorine atoms and single-bonded to two chlorine atoms, with each chlorine atom having two lone pairs.
D
A central carbon atom triple-bonded to one chlorine atom and single-bonded to three chlorine atoms, with each chlorine atom having three lone pairs.
Verified step by step guidance
1
Identify the central atom in the molecule CCl4. Carbon (C) is less electronegative than chlorine (Cl), so carbon will be the central atom.
Determine the total number of valence electrons available. Carbon has 4 valence electrons, and each chlorine atom has 7 valence electrons. Since there are 4 chlorine atoms, total valence electrons = 4 + (4 × 7) = 32 electrons.
Draw single bonds between the central carbon atom and each of the four chlorine atoms. Each single bond consists of 2 electrons, so 4 bonds use 8 electrons.
Distribute the remaining electrons as lone pairs on the chlorine atoms to complete their octets. Each chlorine needs 8 electrons total (including bonding electrons), so after the single bond, each chlorine will have 6 electrons as lone pairs (3 lone pairs per chlorine).
Check the carbon atom's octet. Carbon shares 4 pairs of bonding electrons (8 electrons total) with the chlorines, satisfying the octet rule. Thus, the Lewis structure is a central carbon atom single-bonded to four chlorine atoms, each chlorine having three lone pairs.