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Multiple Choice
The standard molar entropy for Br₂(g) is 245.46 J/(mol·K) at 25°C. Given that ΔS° = 104.58 J/K for the dissociation of one mole of Br₂(g) into Br(g) at 25°C, find the standard molar entropy for Br(g) at 25°C.
A
122.73 J/(mol·K)
B
177.02 J/(mol·K)
C
350.04 J/(mol·K)
D
245.46 J/(mol·K)
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Verified step by step guidance
1
Understand the reaction: The dissociation of one mole of Br₂(g) into Br(g) can be represented as Br₂(g) → 2Br(g).
Apply the formula for the change in standard entropy (ΔS°) for the reaction: ΔS° = ΣS°(products) - ΣS°(reactants).
Identify the given values: The standard molar entropy of Br₂(g) is 245.46 J/(mol·K), and ΔS° for the reaction is 104.58 J/K.
Set up the equation using the known values: 104.58 J/K = [2 * S°(Br(g))] - 245.46 J/(mol·K).
Solve for S°(Br(g)): Rearrange the equation to find S°(Br(g)) by isolating it on one side of the equation.