Molecular Orbital Theory definitions Flashcards
Molecular Orbital Theory definitions
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Molecular Orbital
A region in a molecule where atomic orbitals combine, forming bonding or antibonding interactions.Bonding Molecular Orbital
A molecular orbital with high electron density that promotes bond formation and increases stability.Antibonding Molecular Orbital
A molecular orbital with a node of low electron density that prevents bond formation and decreases stability.Sigma (σ) Orbital
A type of bonding molecular orbital characterized by high electron density along the axis connecting two nuclei.Sigma Star (σ*) Orbital
An antibonding molecular orbital with a node, reducing electron density and bond stability.Node
A region in an antibonding molecular orbital where electron density is minimal, hindering bond formation.Aufbau Principle
A rule stating electrons fill atomic orbitals from lowest to highest energy levels.Pauli Exclusion Principle
A principle stating each orbital can hold two electrons with opposite spins.Hund's Rule
A rule stating degenerate orbitals are singly filled before pairing electrons.Electron Delocalization
The spreading of electrons across multiple atoms in a molecule, enhancing stability.Valence Electrons
Electrons in the outermost shell of an atom, involved in forming molecular orbitals.Atomic Orbital
A region around an atom's nucleus where electrons are likely to be found.Spin Quantum Number
A quantum number indicating the intrinsic angular momentum of an electron.Degenerate Orbitals
Orbitals with the same energy level, filled singly before pairing according to Hund's Rule.Electron Orbital Diagram
A visual representation of electron distribution in atomic or molecular orbitals.