When you shine light of band gap energy or higher on a semiconductor and promote electrons from the valence band to the conduction band, do you expect the conductivity of the semiconductor to (a) remain unchanged, (b) increase, or (c) decrease?

Name: Chemistry: The Central Science
Author: Brown
ISBN: 9780134414232

Verified step by step guidance

Step 1: Understand the structure of a semiconductor. Semiconductors have a valence band filled with electrons and a conduction band that is typically empty. The energy gap between these two bands is known as the band gap.

Step 2: Consider what happens when light with energy equal to or greater than the band gap is shone on the semiconductor. This energy can excite electrons from the valence band to the conduction band.

Step 3: Recognize that when electrons are promoted to the conduction band, they leave behind holes in the valence band. Both the electrons in the conduction band and the holes in the valence band can contribute to electrical conductivity.

Step 4: Analyze the effect of increased charge carriers. With more electrons in the conduction band and more holes in the valence band, the number of charge carriers increases, which typically enhances the material's ability to conduct electricity.

Step 5: Conclude that the conductivity of the semiconductor is expected to increase when light of band gap energy or higher is shone on it, due to the increased number of charge carriers.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Band Gap Energy

Band gap energy is the energy difference between the valence band, where electrons are normally present, and the conduction band, where electrons can move freely and contribute to electrical conductivity. In semiconductors, this gap is small enough that when energy, such as light, is applied, electrons can be excited from the valence band to the conduction band, allowing for increased conductivity.

Electron Promotion

Electron promotion refers to the process of moving electrons from a lower energy state (valence band) to a higher energy state (conduction band) when sufficient energy is provided. This transition is crucial in semiconductors, as it directly affects their ability to conduct electricity. The promotion of electrons increases the number of charge carriers available for conduction, thereby enhancing the material's conductivity.

Conductivity in Semiconductors

Conductivity in semiconductors is a measure of how easily electric current can flow through the material. It is influenced by the number of charge carriers (electrons and holes) present. When light of sufficient energy is shone on a semiconductor, it promotes electrons to the conduction band, increasing the number of free charge carriers and thus raising the conductivity of the semiconductor.

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