The standard enthalpies of formation of gaseous propyne (C3H4), propylene (C3H6), and propane (C3H8) are +185.4, +20.4, and -103.8 kJ/mol, respectively. (c) Which is the most efficient fuel in terms of heat evolved per unit mass?

Two positively charged spheres, each with a charge of 2.0⨉10-5 C, a mass of 1.0 kg, and separated by a distance of 1.0 cm, are held in place on a frictionless track. (a) What is the electrostatic potential energy of this system?
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Key Concepts
Electrostatic Potential Energy
Coulomb's Law
Units of Charge and Energy
Consider a system consisting of the following apparatus, in which gas is confined in one flask and there is a vacuum in the other flask. The flasks are separated by a valve. Assume that the flasks are perfectly insulated and will not allow the flow of heat into or out of the flasks to the surroundings. When the valve is opened, gas flows from the filled flask to the evacuated one. (a) Is work performed during the expansion of the gas? (b) Why or why not?
A system consists of a sample of gas contained in a cylinder-and-piston arrangement. It undergoes the change in state shown in the drawing under two different situations: In Case 1, the cylinder and piston are perfect thermal insulators that do not allow heat to be transferred. In Case 2, the cylinder and piston are made up of a thermal conductor such as a metal, and during the state change, the cylinder gets warmer to the touch. Let 𝑞1,𝑤1, and Δ𝐸1 be the values of q, w, and Δ𝐸 for Case 1, and let 𝑞2,𝑤2, and Δ𝐸2 be the values for Case 2. b. What is the sign of 𝑤1?
The heat of combustion of ethanol, C2H5OH(l), is -1367 kJ/mol. A batch of Sauvignon Blanc wine contains 10.6% ethanol by mass. Assuming the density of the wine to be 1.0 g/mL, what is the caloric content due to the alcohol (ethanol) in a 6-oz glass of wine (177 mL)?
The heat of combustion of fructose, C6H12O6, is -2812 kJ/mol. If a fresh golden delicious apple weighing 4.23 oz (120 g) contains 16.0 g of fructose, what caloric content does the fructose contribute to the apple?
The air bags that provide protection in automobiles in the event of an accident expand because of a rapid chemical reaction. From the viewpoint of the chemical reactants as the system, what do you expect for the signs of q and w in this process?
