Here are the essential concepts you must grasp in order to answer the question correctly.
Chitin Structure
Chitin is a long-chain polymer of N-acetylglucosamine, a derivative of glucose. Its structure is similar to that of cellulose, featuring a linear arrangement of sugar molecules linked by β(1→4) glycosidic bonds. This unique structure provides strength and rigidity, making it a key component in the exoskeletons of arthropods like shrimp.
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Digestive Enzymes
Humans lack the specific enzymes required to break down chitin, such as chitinase. While we can digest polysaccharides like amylose and cellulose due to the presence of amylase and cellulase, respectively, the absence of chitinase means that chitin remains largely undigested in the human gastrointestinal tract.
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Comparison with Amylose and Cellulose
Amylose is a component of starch, composed of α(1→4) linked glucose units, making it digestible by human enzymes. In contrast, cellulose, like chitin, has β(1→4) linkages but is also indigestible for humans. This comparison highlights the structural differences that determine whether a polysaccharide can be broken down by human digestive systems.