An electron in a one-dimensional box has ground state energy eV. What is the wavelength of the photon absorbed when the electron makes a transition to the second excited state?
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35. Special Relativity
Inertial Reference Frames
Problem 27
Textbook Question
(a) An electron with initial kinetic energy eV encounters a square barrier with height eV and width nm. What is the probability that the electron will tunnel through the barrier?
(b) A proton with the same kinetic energy encounters the same barrier. What is the probability that the proton will tunnel through the barrier?

1
Step 1: Begin by understanding the concept of quantum tunneling. Quantum tunneling occurs when a particle passes through a potential barrier that it classically does not have enough energy to overcome. The probability of tunneling is determined using the Schrödinger equation and depends on the particle's mass, energy, and the barrier's properties.
Step 2: For part (a), calculate the wave number inside the barrier for the electron using the formula: , where is the mass of the electron, is the barrier height, is the particle's energy, and is the reduced Planck constant.
Step 3: Use the tunneling probability formula: , where is the width of the barrier and is the wave number calculated in Step 2. Substitute the values for the electron's mass, energy, barrier height, and width to find the tunneling probability.
Step 4: For part (b), repeat the process for the proton. Since the proton has a much larger mass than the electron, its wave number will be different. Use the same formula for and substitute the proton's mass instead of the electron's mass.
Step 5: Calculate the tunneling probability for the proton using the same formula: . Compare the probabilities for the electron and proton to understand the effect of mass on tunneling probability.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Quantum Tunneling
Quantum tunneling is a phenomenon in quantum mechanics where a particle has a probability of passing through a potential energy barrier, even if its energy is less than the height of the barrier. This occurs because particles exhibit wave-like properties, allowing them to exist in a superposition of states, which can lead to a non-zero probability of being found on the other side of the barrier.
Barrier Penetration Probability
The probability of a particle tunneling through a barrier can be calculated using the transmission coefficient, which depends on the height and width of the barrier as well as the energy of the particle. For a rectangular barrier, this probability decreases exponentially with increasing barrier height and width, making it less likely for particles with lower energy to tunnel through.
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Mass and Energy Relationship
In quantum mechanics, the mass of a particle affects its wave function and, consequently, its tunneling probability. Heavier particles, like protons, have a shorter wavelength compared to lighter particles, like electrons, which influences their ability to tunnel through barriers. This means that for the same kinetic energy, a proton will generally have a lower tunneling probability than an electron when encountering the same barrier.
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