3 moles of an ideal gas are in the left side of an hourglass-shaped container, separated by a thin barrier. The right side is completely empty, but the volume of the left and right sides are equal. The barrier is suddenly removed, and the gas freely expands into the vacuum. What is the change in entropy?
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23. The Second Law of Thermodynamics
Entropy Equations for Special Processes
Problem 58
Textbook Question
Determine the work available in a 2.2-kg block of copper at 490 K if the surroundings are at 290 K. Use results of Problem 57.

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Identify the key concept: The problem involves calculating the maximum work available, which is related to the change in entropy and the Carnot efficiency. The work available is determined by the thermodynamic principles of heat transfer and entropy changes.
Determine the heat capacity of copper: From Problem 57 (assumed to be referenced), the specific heat capacity of copper, \( c \), is likely provided. If not, use the standard value \( c = 385 \; \text{J/kg·K} \).
Calculate the heat energy \( Q \) absorbed by the copper block as it cools from 490 K to 290 K: Use the formula \( Q = m c \Delta T \), where \( m \) is the mass of the block, \( c \) is the specific heat capacity, and \( \Delta T = T_{initial} - T_{final} \).
Determine the entropy change \( \Delta S \): Use the formula \( \Delta S = \int \frac{dQ}{T} \). For a constant heat capacity, this simplifies to \( \Delta S = m c \ln\left(\frac{T_{final}}{T_{initial}}\right) \).
Calculate the maximum work available: The maximum work is given by \( W_{max} = Q - T_{surroundings} \Delta S \), where \( T_{surroundings} \) is the temperature of the surroundings (290 K). Substitute the values of \( Q \) and \( \Delta S \) to find the result.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Thermodynamics
Thermodynamics is the branch of physics that deals with heat, work, temperature, and the laws governing energy transfer. It is essential for understanding how energy is converted from one form to another and how it affects matter. In this context, the principles of thermodynamics will help determine the work available from the copper block based on its temperature and the surrounding environment.
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The First Law of Thermodynamics
Heat Transfer
Heat transfer refers to the movement of thermal energy from one object or system to another due to a temperature difference. It can occur through conduction, convection, or radiation. In the given problem, understanding how heat flows between the copper block at 490 K and its surroundings at 290 K is crucial for calculating the work that can be extracted from the system.
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Overview of Heat Transfer
Carnot Efficiency
Carnot efficiency is a theoretical maximum efficiency for a heat engine operating between two temperatures, defined by the formula η = 1 - (T_cold/T_hot). This concept is vital for determining the maximum work output from a thermal system. In this scenario, applying Carnot's principles will allow for the calculation of the work available from the copper block based on its temperature relative to the surroundings.
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