Your friend claims they have a design for a reversible heat engine that can operate between the freezing and boiling temperatures of water that has an efficiency of 30%. Is this possible?
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23. The Second Law of Thermodynamics
The Carnot Cycle
Problem 12c
Textbook Question
A Carnot engine is operated between two heat reservoirs at temperatures of 520 K and 300 K. What is the thermal efficiency of the engine?

1
Understand the concept of a Carnot engine: A Carnot engine is an idealized heat engine that operates between two heat reservoirs and has the maximum possible efficiency. The efficiency of a Carnot engine depends only on the temperatures of the two reservoirs.
Identify the temperatures of the heat reservoirs: In this problem, the high-temperature reservoir (T₁) is at 520 K, and the low-temperature reservoir (T₂) is at 300 K.
Recall the formula for the thermal efficiency of a Carnot engine: The efficiency (η) is given by the equation η = 1 - (T₂/T₁), where T₁ is the temperature of the hot reservoir and T₂ is the temperature of the cold reservoir.
Substitute the given temperatures into the efficiency formula: Replace T₁ with 520 K and T₂ with 300 K in the equation η = 1 - (T₂/T₁).
Simplify the expression: Perform the division and subtraction to find the efficiency in decimal form, which can be converted to a percentage by multiplying by 100.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Carnot Engine
A Carnot engine is a theoretical thermodynamic cycle that is considered the most efficient possible engine. It operates between two heat reservoirs, absorbing heat from the high-temperature reservoir and expelling heat to the low-temperature reservoir, while performing work. The efficiency of a Carnot engine depends solely on the temperatures of these reservoirs.
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Thermal Efficiency
Thermal efficiency is a measure of how well an engine converts heat into work. For a Carnot engine, it is calculated using the formula: efficiency = 1 - (T_cold/T_hot), where T_cold and T_hot are the absolute temperatures of the cold and hot reservoirs, respectively. This formula shows that efficiency increases as the temperature difference between the reservoirs increases.
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Thermal Efficiency & The Second Law of Thermodynamics
Absolute Temperature
Absolute temperature is measured in Kelvin, which is the SI unit for temperature. It starts at absolute zero, the point where all molecular motion ceases. In thermodynamics, using Kelvin is crucial because it allows for direct calculations of efficiency and other properties without negative values, ensuring accurate and meaningful results.
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