Six moles of an ideal gas are in a cylinder fitted at one end with a movable piston. The initial temperature of the gas is °C and the pressure is constant. As part of a machine design project, calculate the final temperature of the gas after it has done J of work.
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22. The First Law of Thermodynamics
First Law of Thermodynamics
Problem 91b
Textbook Question
A scuba diver releases a 3.60-cm-diameter (spherical) bubble of air from a depth of 14.0 m. Assume the temperature is constant at 298 K, and that the air behaves as an ideal gas. Sketch a PV diagram for the process. Take the density of water to be 1000 kg/m3.

1
Understand the problem: The scuba diver releases a spherical bubble of air from a depth of 14.0 m. The pressure at this depth is higher due to the water column above the bubble. As the bubble rises, the pressure decreases, causing the bubble to expand. We are tasked with sketching a PV diagram for this process, where P is the pressure and V is the volume of the bubble.
Step 1: Calculate the pressure at the depth of 14.0 m. The total pressure at this depth is the sum of the atmospheric pressure at the surface (P₀) and the pressure due to the water column. Use the formula: , where is the density of water, is the acceleration due to gravity, and is the depth.
Step 2: Relate the pressure and volume of the bubble using the ideal gas law. Since the temperature is constant, the process is isothermal. For an isothermal process, the relationship between pressure and volume is given by: , where and are the pressure and volume at the initial depth, and and are the pressure and volume at the surface.
Step 3: Express the volume of the bubble as a function of its diameter. The volume of a sphere is given by: , where is the radius of the bubble. The radius can be calculated from the given diameter of 3.60 cm.
Step 4: Sketch the PV diagram. On the PV diagram, the x-axis represents the volume (V), and the y-axis represents the pressure (P). Since the process is isothermal, the curve will be a hyperbolic shape, showing that as the pressure decreases, the volume increases. Label the initial point (P₁, V₁) at the depth of 14.0 m and the final point (P₂, V₂) at the surface.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Ideal Gas Law
The Ideal Gas Law relates the pressure, volume, and temperature of an ideal gas through the equation PV = nRT. In this scenario, the bubble of air behaves as an ideal gas, allowing us to apply this law to understand how its volume changes as it rises to the surface, where pressure decreases.
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Hydrostatic Pressure
Hydrostatic pressure is the pressure exerted by a fluid at equilibrium due to the force of gravity. For the scuba diver's bubble, the pressure at a depth of 14.0 m can be calculated using the formula P = ρgh, where ρ is the density of water, g is the acceleration due to gravity, and h is the depth. This pressure affects the initial conditions of the bubble.
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PV Diagram
A PV diagram is a graphical representation of the relationship between pressure (P) and volume (V) for a gas. In this case, the diagram will illustrate the changes in pressure and volume of the air bubble as it ascends from the depth of 14.0 m to the surface, showing how the gas expands as the external pressure decreases.
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