At what cold-reservoir temperature (in ℃) would a Carnot engine with a hot-reservoir temperature of 427℃ have an efficiency of 60%?
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23. The Second Law of Thermodynamics
The Carnot Cycle
Problem 18
Textbook Question
The working substance of a certain Carnot engine is 1.0 mol of an ideal monatomic gas. During the isothermal expansion portion of this engine’s cycle, the volume of the gas doubles, while during the adiabatic expansion the volume increases by a factor of 6.2. The work output of the engine is 920 J in each cycle. Compute the temperatures of the two reservoirs between which this engine operates.

1
Identify the key processes in the Carnot cycle: isothermal expansion, adiabatic expansion, isothermal compression, and adiabatic compression. For this problem, focus on the isothermal and adiabatic processes described.
For the isothermal expansion, use the ideal gas law and the formula for work done during isothermal processes: \( W_{iso} = nRT_H \ln \left( \frac{V_f}{V_i} \right) \), where \( T_H \) is the temperature of the hot reservoir, \( V_f \) and \( V_i \) are the final and initial volumes, \( n \) is the number of moles, and \( R \) is the gas constant.
For the adiabatic expansion, use the relationship between temperature and volume for an adiabatic process: \( T V^{\gamma - 1} = \text{constant} \), where \( \gamma = \frac{C_p}{C_v} \) is the adiabatic index. For a monatomic gas, \( \gamma = \frac{5}{3} \). Use this to relate the temperatures and volumes during the adiabatic expansion.
The total work output of the Carnot engine is given as 920 J. Use the efficiency formula for a Carnot engine: \( \eta = 1 - \frac{T_C}{T_H} \), where \( T_C \) is the temperature of the cold reservoir. Combine this with the work expressions to solve for \( T_H \) and \( T_C \).
Substitute the known values (\( n = 1.0 \) mol, \( V_f/V_i = 2 \) for isothermal expansion, \( V_f/V_i = 6.2 \) for adiabatic expansion, and \( W = 920 \) J) into the equations derived in the previous steps to calculate the temperatures of the two reservoirs.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Carnot Engine
A Carnot engine is an idealized thermodynamic cycle that provides the maximum possible efficiency for a heat engine operating between two temperature reservoirs. It consists of two isothermal processes (heat absorption and rejection) and two adiabatic processes (expansion and compression). The efficiency of a Carnot engine depends solely on the temperatures of the hot and cold reservoirs, making it a benchmark for real engines.
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Entropy of Carnot Engine
Ideal Gas Law
The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of an ideal gas through the equation PV = nRT. In the context of the Carnot engine, this law helps determine the changes in temperature and pressure during the isothermal and adiabatic processes, allowing for the calculation of the temperatures of the reservoirs based on the gas's behavior.
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Ideal Gases and the Ideal Gas Law
Work Done by a Gas
The work done by a gas during expansion or compression can be calculated using the formula W = ∫PdV, where P is the pressure and V is the volume. In the case of isothermal expansion, the work done is related to the temperature and the change in volume. Understanding how to calculate work is crucial for analyzing the performance of the Carnot engine and determining the temperatures of the reservoirs.
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Calculating Work Done on Monoatomic Gas
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