The thermal energy of 1.0 mol of a substance is increased by 1.0 J. What is the temperature change if the system is (a) a monatomic gas, (b) a diatomic gas, and (c) a solid?
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21. Kinetic Theory of Ideal Gases
Internal Energy of Gases
Problem 48c
Textbook Question
Interstellar space, far from any stars, is filled with a very low density of hydrogen atoms (H, not H₂). The number density is about 1 atom/cm³ and the temperature is about 3 K. What is the edge length L of an L ✕ L ✕ L cube of gas with 1.0 J of thermal energy?
Verified step by step guidance1
Start by recalling the formula for the thermal energy of an ideal gas: , where is the thermal energy, is the number of particles, is the Boltzmann constant (), and is the temperature in kelvins.
Rearrange the formula to solve for , the number of particles: . Substitute the given values: , , and .
Once is calculated, use the relationship between the number density (particles per unit volume) and the total number of particles: , where is the volume of the cube. Rearrange to find : . The number density is given as , which must be converted to SI units: .
The volume of the cube is related to its edge length by the formula . Solve for : . Substitute the value of obtained in the previous step.
Finally, ensure all units are consistent (e.g., meters for ) and verify the calculation steps to confirm the edge length of the cube.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Thermal Energy
Thermal energy is the total kinetic energy of the particles in a substance due to their motion. In the context of gases, it is related to temperature and can be quantified using the equation E = (3/2)nRT for ideal gases, where E is the thermal energy, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin.
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Volume Thermal Expansion
Ideal Gas Law
The Ideal Gas Law is a fundamental equation in thermodynamics that relates pressure, volume, temperature, and the number of moles of a gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature. This law helps in understanding the behavior of gases under various conditions.
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Ideal Gases and the Ideal Gas Law
Volume and Density
Volume is the amount of space occupied by a substance, and in this case, it is represented by the cube's edge length L, where the volume V = L³. Density, defined as mass per unit volume, is crucial for determining how many particles are present in a given volume, which directly affects the thermal energy and behavior of the gas in interstellar space.
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Problems with Mass, Volume, & Density
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