The graph in Fig. E shows a -diagram of the air in a human lung when a person is inhaling and then exhaling a deep breath. Such graphs, obtained in clinical practice, are normally somewhat curved, but we have modeled one as a set of straight lines of the same general shape. (Important: The pressure shown is the gauge pressure, not the absolute pressure.) The process illustrated here is somewhat different from those we have been studying, because the pressure change is due to changes in the amount of gas in the lung, not to temperature changes. (Think of your own breathing. Your lungs do not expand because they've gotten hot.) If the temperature of the air in the lung remains a reasonable °C, what is the maximum number of moles in this person's lung during a breath?
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22. The First Law of Thermodynamics
Cyclic Thermodynamic Processes
Problem 55a
Textbook Question
A heat engine using a diatomic gas follows the cycle shown in FIGURE P21.55. Its temperature at point 1 is 20℃. Determine Ws, Q, and ∆Eth for each of the three processes in this cycle. Display your results in a table.


1
Step 1: Understand the problem and identify the cycle. The problem involves a heat engine using a diatomic gas undergoing a thermodynamic cycle. The cycle consists of three processes, and we need to calculate the work done (Wₛ), heat transfer (Q), and change in internal energy (∆Eₜₕ) for each process. Recall that for a diatomic gas, the degrees of freedom affect the specific heat capacities.
Step 2: Apply the first law of thermodynamics for each process. The first law states that ΔEₜₕ = Q - Wₛ, where ΔEₜₕ is the change in internal energy, Q is the heat added to the system, and Wₛ is the work done by the system. This relationship will be used to calculate the required quantities for each process.
Step 3: Analyze each process in the cycle. For example: (a) If the process is isothermal, the temperature remains constant, and the change in internal energy (ΔEₜₕ) is zero. Use the formula for work done during isothermal expansion or compression: Wₛ = nRT ln(V₂/V₁). (b) If the process is adiabatic, Q = 0, and the work done can be calculated using the adiabatic relation. (c) If the process is isochoric, the volume remains constant, and Wₛ = 0. Use Q = nCᵥΔT to calculate the heat transfer.
Step 4: Use the specific heat capacities for a diatomic gas. For a diatomic gas, the molar specific heat at constant volume (Cᵥ) is (5/2)R, and the molar specific heat at constant pressure (Cₚ) is (7/2)R. These values will be used to calculate Q and ΔEₜₕ for the processes where temperature changes.
Step 5: Organize the results in a table. After calculating Wₛ, Q, and ΔEₜₕ for each process, display the results in a table format with rows corresponding to the processes and columns for Wₛ, Q, and ΔEₜₕ. Ensure all calculations are consistent with the thermodynamic principles and the given initial conditions (e.g., temperature at point 1 is 20℃).

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Heat Engine
A heat engine is a device that converts thermal energy into mechanical work by exploiting the temperature difference between a hot reservoir and a cold reservoir. It operates in a cyclic process, absorbing heat from the hot reservoir, performing work, and releasing some heat to the cold reservoir. The efficiency of a heat engine is determined by the ratio of work output to heat input.
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First Law of Thermodynamics
The First Law of Thermodynamics states that energy cannot be created or destroyed, only transformed from one form to another. In the context of a heat engine, this law can be expressed as ΔU = Q - W, where ΔU is the change in internal energy, Q is the heat added to the system, and W is the work done by the system. This principle is essential for analyzing energy transfers in thermodynamic processes.
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Diatomic Gas Properties
Diatomic gases, such as nitrogen or oxygen, have unique thermodynamic properties due to their molecular structure, which allows for rotational and vibrational modes of energy storage. This affects their specific heat capacities, which are crucial for calculating heat transfer and work done during processes. Understanding these properties is vital for accurately determining the thermodynamic quantities in the heat engine cycle.
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Properties of Cyclic Thermodynamic Processes
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