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Multiple Choice
Which of the following statements correctly describes the electron configuration of the central oxygen atom in the hydronium ion (H3O+)?
A
It has a complete 3d subshell and an incomplete 2p subshell.
B
It has electrons occupying the 3d subshell.
C
It has a complete 2p subshell and no electrons in the 3d subshell.
D
It has an incomplete 2p subshell due to the positive charge.
Verified step by step guidance
1
Step 1: Identify the central atom and its ground-state electron configuration. Oxygen (O) has an atomic number of 8, so its ground-state electron configuration is $1s^2 2s^2 2p^4$.
Step 2: Understand the effect of the hydronium ion (H3O+) formation on the oxygen atom's electron count. The hydronium ion has a positive charge, meaning one electron is removed compared to the neutral species.
Step 3: Determine how the positive charge affects the oxygen's valence electrons. Since the positive charge is on the entire ion, the oxygen atom effectively has one fewer electron, so it has 7 valence electrons instead of 8.
Step 4: Analyze the occupancy of the 2p and 3d subshells. Oxygen's electrons fill up to the 2p subshell; the 3d subshell is not occupied in the ground state or in common ions like H3O+ because oxygen is in period 2 and does not have 3d electrons.
Step 5: Conclude that the oxygen atom in H3O+ has an incomplete 2p subshell due to the positive charge and no electrons in the 3d subshell, so the correct description is that it has an incomplete 2p subshell and no electrons in the 3d subshell.