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Multiple Choice
Which of the following conditions indicates that a chemical reaction is spontaneous at constant temperature and pressure?
A
ΔG < 0
B
ΔH > TΔS
C
ΔG > 0
D
ΔG = 0
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1
Understand the concept of Gibbs Free Energy (ΔG). It is a thermodynamic quantity that can predict the spontaneity of a reaction at constant temperature and pressure.
Recall the Gibbs Free Energy equation: , where ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
A reaction is spontaneous if ΔG is less than zero (). This indicates that the process can occur without any input of energy.
If ΔG equals zero (), the system is at equilibrium, meaning the forward and reverse reactions occur at the same rate.
If ΔG is greater than zero (), the reaction is non-spontaneous, requiring energy input to proceed.