Join thousands of students who trust us to help them ace their exams!
Multiple Choice
Which of the following conditions indicates that a chemical reaction is spontaneous at constant temperature and pressure?
A
ΔH > TΔS
B
ΔG < 0
C
ΔG > 0
D
ΔG = 0
0 Comments
Verified step by step guidance
1
Understand the concept of Gibbs Free Energy (ΔG), which is used to determine the spontaneity of a reaction. A negative ΔG indicates a spontaneous reaction.
Recall the Gibbs Free Energy equation: ΔG = ΔH - TΔS, where ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
Analyze the given condition: ΔH > TΔS. This implies that the enthalpy change is greater than the product of temperature and entropy change.
Substitute the condition into the Gibbs Free Energy equation: ΔG = ΔH - TΔS. If ΔH > TΔS, then ΔG will be positive, indicating a non-spontaneous reaction.
Conclude that for a reaction to be spontaneous at constant temperature and pressure, ΔG must be less than zero (ΔG < 0), not greater than zero.