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Multiple Choice
Which of the following methods would increase the solubility of a gas in water?
A
Increasing the temperature of the water
B
Decreasing the pressure above the solution
C
Decreasing the temperature of the water
D
Adding a salt to the solution
Verified step by step guidance
1
Recall Henry's Law, which states that the solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid. Mathematically, this is expressed as $C = k_H \times P$, where $C$ is the concentration (solubility) of the gas, $k_H$ is Henry's law constant, and $P$ is the partial pressure of the gas.
Understand the effect of temperature on gas solubility: Generally, the solubility of gases in water decreases as temperature increases because gas molecules gain kinetic energy and escape more easily from the solution.
Analyze the effect of pressure changes: Increasing the pressure above the solution increases gas solubility, while decreasing the pressure reduces it, according to Henry's Law.
Consider the effect of adding salt (salting out effect): Adding salt to water usually decreases the solubility of gases because the salt ions compete with gas molecules for space in the solvent.
Conclude that to increase the solubility of a gas in water, you should decrease the temperature or increase the pressure above the solution, but not add salt.