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Multiple Choice
Which of the following best represents the Lewis dot structure for neutral H3PO4 (phosphoric acid)?
A
A central P atom bonded to four H atoms and one O atom, with all atoms having complete octets.
B
A central P atom bonded to two O atoms (one double-bonded), and three H atoms directly bonded to P.
C
A central P atom bonded to three O atoms, each O atom bonded to an H atom, and one lone pair on P.
D
A central P atom bonded to four O atoms, one of which is double-bonded; three O atoms each bonded to an H atom, with all atoms having complete octets.
Verified step by step guidance
1
Identify the central atom in H3PO4, which is phosphorus (P), because it is less electronegative than oxygen and hydrogen and can form multiple bonds.
Determine the total number of valence electrons: phosphorus has 5, each oxygen has 6, and each hydrogen has 1. Calculate the sum for all atoms in H3PO4.
Arrange the atoms with phosphorus in the center, bonded to four oxygen atoms. Three of these oxygen atoms will be bonded to hydrogen atoms (forming OH groups), and one oxygen will be double-bonded to phosphorus.
Distribute the remaining valence electrons to satisfy the octet rule for oxygen and phosphorus atoms, remembering that phosphorus can have an expanded octet (more than 8 electrons).
Verify that all hydrogen atoms have one bond (duet rule), all oxygen atoms have complete octets, and phosphorus has a stable structure with one double bond to oxygen and three single bonds to oxygen atoms that are each bonded to hydrogen.