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Multiple Choice
Which of the following correctly represents the orbital diagram for a neutral sulfur atom?
A
1s: ↑↓ 2s: ↑↓ 2p: ↑↓ ↑↓ ↑↓ 3s: ↑↓ 3p: ↑↓ ↑ ↑
B
1s: ↑↓ 2s: ↑↓ 2p: ↑↓ ↑↓ ↑↓ 3s: ↑↓ 3p: ↑↓ ↑↓ ↑
C
1s: ↑↓ 2s: ↑↓ 2p: ↑↓ ↑↓ ↑↓ 3s: ↑↓ 3p: ↑↓ ↑↓ ↑↓
D
1s: ↑↓ 2s: ↑↓ 2p: ↑↓ ↑↓ ↑↓ 3s: ↑↓ 3p: ↑ ↑ ↑
Verified step by step guidance
1
Step 1: Determine the atomic number of sulfur, which is 16. This means a neutral sulfur atom has 16 electrons to place in orbitals.
Step 2: Fill the orbitals in order of increasing energy using the Aufbau principle: 1s, 2s, 2p, 3s, then 3p.
Step 3: Apply the Pauli exclusion principle and Hund's rule when filling orbitals. Each orbital can hold a maximum of two electrons with opposite spins, and electrons fill degenerate orbitals singly first with parallel spins.
Step 4: Fill the orbitals with electrons: 1s holds 2 electrons (↑↓), 2s holds 2 electrons (↑↓), 2p holds 6 electrons (↑↓ ↑↓ ↑↓), 3s holds 2 electrons (↑↓), and 3p holds the remaining 4 electrons.
Step 5: Distribute the 4 electrons in the 3p orbitals according to Hund's rule: place one electron in each of the three 3p orbitals first (all with parallel spins), then pair the fourth electron in one of the 3p orbitals.