Problem 94
How many fluorine atoms are present in 45.3 g of C2F4?
Problem 96a
A chemist decomposes samples of several compounds; the masses of their constituent elements are listed. Calculate the empirical formula for each compound. a. 1.245 g Ni, 5.381 g I
Problem 96b
A chemist decomposes samples of several compounds; the masses of their constituent elements are listed. Calculate the empirical formula for each compound. b. 2.677 g Ba, 3.115 g Br
Problem 96c
A chemist decomposes samples of several compounds; the masses of their constituent elements are listed. Calculate the empirical formula for each compound. c. 2.128 g Be, 7.557 g S, 15.107 g O
Problem 97a
Calculate the empirical formula for each stimulant based on its elemental mass percent composition.
a. nicotine (found in tobacco leaves): C 74.03%, H 8.70%, N 17.27%
b. caffeine (found in coffee beans): C 49.48%, H 5.19%, N 28.85%, O 16.48%
Problem 98a
Calculate the empirical formula for each natural flavor based on its elemental mass percent composition. a. methyl butyrate (component of apple taste and smell): C 58.80%, H 9.87%, O 31.33%
Problem 98b
Calculate the empirical formula for each natural flavor based on its elemental mass percent composition. b. vanillin (responsible for the taste and smell of vanilla): C 63.15%, H 5.30%, O 31.55%
Problem 99
The elemental mass percent composition of ibuprofen (a nonsteroidal anti-inflammatory drug [NSAID]) is 75.69% C, 8.80% H, and 15.51% O. Determine the empirical formula of ibuprofen.
Problem 100
The elemental mass percent composition of ascorbic acid (vitamin C) is 40.92% C, 4.58% H, and 54.50% O. Determine the empirical formula of ascorbic acid.
- What is the empirical formula of nitrogen chloride given that a 0.77 mg sample of nitrogen reacts with chlorine to form 6.61 mg of the chloride?
Problem 101
Problem 102
A 45.2-mg sample of phosphorus reacts with selenium to form 131.6 mg of the selenide. Determine the empirical formula of phosphorus selenide.
Problem 104a
From the given molar mass and empirical formula of several compounds, find the molecular formula of each compound. a. C4H9, 114.22 g/mol
Problem 104b
From the given molar mass and empirical formula of several compounds, find the molecular formula of each compound. b. CCl, 284.77 g/mol
Problem 105
Combustion analysis of a hydrocarbon produces 33.01 g CO2 and 13.51 g H2O. Calculate the empirical formula of the hydrocarbon.
Problem 106
Combustion analysis of naphthalene, a hydrocarbon used in mothballs, produces 8.80 g CO2 and 1.44 g H2O. Calculate the empirical formula of naphthalene.
Problem 107
The foul odor of rancid butter is due largely to butyric acid, a compound containing carbon, hydrogen, and oxygen. Combustion analysis of a 4.30-g sample of butyric acid produces 8.59 g CO2 and 3.52 g H2O. Determine the empirical formula of butyric acid.
Problem 108
Tartaric acid is the white, powdery substance that coats tart candies such as Sour Patch Kids. Combustion analysis of a 12.01-g sample of tartaric acid—which contains only carbon, hydrogen, and oxygen—produces 14.08 g CO2 and 4.32 g H2O. Determine the empirical formula of tartaric acid.
- Classify each compound as organic or inorganic: a. CaCO3 b. C4H8 c. C4H6O6 d. LiF
Problem 109
Problem 112
Classify each hydrocarbon as an alkane, alkene, or alkyne. a. HC≡CH
- Write the formula based on the name, or the name based on the formula, for each hydrocarbon. a. propane b. CH3CH2CH3 c. CH3CH2CH2CH2CH3 d. octane
Problem 113
- Write the formula based on the name, or the name based on the formula, for each hydrocarbon: a. CH3CH3 b. pentane c. CH3CH2CH2CH2CH2CH3 d. heptane.
Problem 114
- Classify each organic compound as a hydrocarbon or a functionalized hydrocarbon. For functionalized hydrocarbons, identify the compound’s family. a. H3C-CH2OH
Problem 115
Problem 118
A drop of water has a volume of approximately 0.05 mL. How many water molecules does it contain? The density of water is 1.0 g/cm3.
Problem 121b
Determine the chemical formula of each compound and then use it to calculate the mass percent composition of each constituent element. a. potassium chromate b. lead(II) phosphate
Problem 121c
Determine the chemical formula of each compound and then use it to calculate the mass percent composition of each constituent element. c. sulfurous acid
Problem 122
Determine the chemical formula of each compound and then use it to calculate the mass percent composition of each constituent element. c. nitrogen triiodide
Problem 123
A Freon leak in the air-conditioning system of an old car releases 38.0 g of CF2Cl2 per month. What mass of chlorine does this car emit into the atmosphere each year?
Problem 123d
Determine the chemical formula of each compound and then use it to calculate the mass percent composition of each constituent element. d. cobalt(II) bromide
Problem 125
A metal (M) forms a compound with the formula MCl3. If the compound contains 65.57% Cl by mass, what is the identity of the metal?
Problem 126
A metal (M) forms an oxide with the formula M2O. If the oxide contains 16.99% O by mass, what is the identity of the metal?
Ch.3 - Molecules and Compounds
