Chapter 4: Atoms and Elements

Introduction

This chapter explores the fundamental building blocks of matter—atoms and elements. It covers the classification of matter, the structure of atoms, the organization of the periodic table, and the trends in elemental properties. Understanding these concepts is essential for further study in chemistry and its applications in fields such as agriculture, health, and materials science.

Classification of Matter

Pure Substances and Mixtures

• Pure substances are materials made of only one type of particle; they include elements and compounds.

• Mixtures contain two or more substances physically combined and can be separated by physical means.

Elements are pure substances from which all other things are built and cannot be broken down into simpler substances.

Elements and Chemical Symbols

Element Names and Symbols

Each element is represented by a unique chemical symbol, usually derived from its English or Latin name. Symbols consist of one or two letters, with the first letter always capitalized.

• Examples: C (carbon), N (nitrogen), F (fluorine), Co (cobalt), Ca (calcium)

Some symbols are based on Latin names, such as Ag (argentum for silver) and Au (aurum for gold).

Examples of Elements

• Carbon (C): Exists in several forms, including graphite, diamond, buckminsterfullerene, and nanotubes.

Mercury (Hg): Chemistry Link to Health

• Mercury is a liquid metal at room temperature and can be toxic to humans through inhalation, skin contact, or ingestion.

• Long-term exposure can damage the brain and kidneys.

The Periodic Table

Organization of the Periodic Table

The periodic table arranges 118 elements into groups (vertical columns) and periods (horizontal rows) based on similar properties and increasing atomic number.

Groups and Periods

• Groups: Vertical columns with similar chemical properties (numbered 1A–8A for representative elements, 1–18 in the IUPAC system).

• Periods: Horizontal rows numbered 1–7.

Special Groups

• Alkali Metals (Group 1A): Highly reactive metals including Li, Na, K, Rb, Cs.

• Halogens (Group 7A): Reactive nonmetals including F, Cl, Br, I, At.

Elements Essential for Life

• 20 elements are essential for human health; O, C, H, and N make up 96% of body mass.

• Macrominerals (e.g., Ca, P, K, Cl, S, Na, Mg) are vital for physiological functions.

The Structure of the Atom

Dalton’s Atomic Theory

• Atoms are tiny particles of matter, unique to each element.

• Atoms combine to form compounds and are rearranged in chemical reactions but are not created or destroyed.

Subatomic Particles

• Protons: Positive charge, located in the nucleus, mass ≈ 1 amu.

• Neutrons: No charge, located in the nucleus, mass ≈ 1 amu.

• Electrons: Negative charge, located outside the nucleus, mass ≈ 0.00055 amu.

Atomic Number and Mass Number

Atomic Number (Z)

• The atomic number is the number of protons in an atom and defines the element.

• For a neutral atom, the number of electrons equals the number of protons.

Mass Number (A)

• The mass number is the sum of protons and neutrons in the nucleus.

• Number of neutrons = mass number – atomic number.

Isotopes and Atomic Mass

Isotopes

• Isotopes are atoms of the same element with different numbers of neutrons and thus different mass numbers.

• Isotopes are represented by their atomic symbol, mass number, and atomic number.

Calculating Atomic Mass

The atomic mass of an element is the weighted average of the masses of its naturally occurring isotopes.

• Atomic mass = (mass of isotope 1 × percent abundance) + (mass of isotope 2 × percent abundance) + ...

Electron Energy Levels

Energy Levels (Shells)

• Electrons occupy energy levels (shells) designated by n = 1, 2, 3, ...

• Each shell can hold a maximum number of electrons:

Subshells and Orbitals

• Each shell contains subshells (s, p, d, f) with specific shapes and capacities.

• Each orbital can hold up to 2 electrons with opposite spins.

Electron Configurations

• Electron configuration describes the arrangement of electrons in shells and subshells.

• Example: Oxygen (O): 1s22s22p4

Trends in Periodic Properties

Valence Electrons and Electron-Dot Symbols

• Valence electrons are the electrons in the outermost shell and determine chemical properties.

• Electron-dot symbols (Lewis structures) represent valence electrons as dots around the element symbol.

Atomic Size

• Atomic size increases down a group and decreases across a period from left to right.

Ionization Energy

• Ionization energy is the energy required to remove an electron from an atom.

• Ionization energy decreases down a group and increases across a period.

Metallic Character

• Metallic character refers to the tendency to lose electrons and form positive ions.

• Metallic character increases down a group and decreases across a period.

Summary of Periodic Trends

Concept Map

The following concept map summarizes the relationships among the main ideas in this chapter, including the classification of elements, atomic structure, and periodic trends.