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Multiple Choice
Which of the following statements correctly describes the Lewis dot structure of a neutral ICl_3 molecule?
A
The central iodine atom has two bonding pairs and three lone pairs of electrons.
B
The central iodine atom has three bonding pairs and two lone pairs of electrons.
C
The central iodine atom has three bonding pairs and no lone pairs of electrons.
D
The central iodine atom has three bonding pairs and one lone pair of electrons.
Verified step by step guidance
1
Identify the total number of valence electrons in the ICl_3 molecule. Iodine (I) is in group 17 and has 7 valence electrons, and each chlorine (Cl) atom also has 7 valence electrons. Since there are three chlorine atoms, calculate the total valence electrons as $7 + 3 \times 7$.
Determine the central atom, which is iodine (I) in this case, and arrange the three chlorine atoms around it, forming three single bonds. Each bond represents a bonding pair of electrons shared between iodine and chlorine.
Count the electrons used in bonding: each single bond contains 2 electrons, so for three bonds, there are $3 \times 2$ bonding electrons.
Subtract the bonding electrons from the total valence electrons to find the number of remaining electrons, which will be placed as lone pairs on the atoms. Since chlorine atoms typically complete their octet with three lone pairs each, assign lone pairs to chlorine atoms first.
Assign any remaining electrons as lone pairs on the central iodine atom. The number of lone pairs on iodine plus the bonding pairs will help you determine the correct Lewis structure description. For ICl_3, iodine ends up with three bonding pairs and two lone pairs of electrons.