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Multiple Choice
Which of the following statements correctly describes the Lewis dot structure of the neutral compound RnCl_4?
A
Rn is surrounded by four single bonds to Cl atoms and has no lone pairs.
B
Rn is bonded to two Cl atoms with single bonds and has three lone pairs.
C
Rn is surrounded by four double bonds to Cl atoms and has no lone pairs.
D
Rn is surrounded by four single bonds to Cl atoms and has two lone pairs of electrons.
Verified step by step guidance
1
Step 1: Identify the valence electrons for each atom in the compound RnCl_4. Radon (Rn) is a noble gas in group 18, so it has 8 valence electrons. Chlorine (Cl) is in group 17, so each Cl atom has 7 valence electrons.
Step 2: Calculate the total number of valence electrons in the molecule by adding the valence electrons of Rn and the four Cl atoms: total electrons = valence electrons of Rn + 4 × valence electrons of Cl.
Step 3: Determine the bonding framework. Since Rn is the central atom, it will form bonds with each of the four Cl atoms. Each single bond consists of 2 electrons, so 4 single bonds use 8 electrons.
Step 4: Assign the remaining electrons as lone pairs. After accounting for bonding electrons, subtract these from the total valence electrons to find how many electrons remain as lone pairs on Rn and Cl atoms. Remember that each Cl atom typically has three lone pairs to complete its octet.
Step 5: Confirm the Lewis structure by checking the octet rule for each atom. Rn can have an expanded octet because it is in period 6, so it can accommodate more than 8 electrons. The correct structure will have Rn bonded to four Cl atoms with single bonds and two lone pairs on Rn, satisfying the octet and total electron count.