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Multiple Choice
Which of the following is the best Lewis dot structure for the neutral compound CH2Cl2?
A
A central carbon atom single-bonded to two hydrogen atoms and two chlorine atoms, with each chlorine atom having two lone pairs.
B
A central carbon atom single-bonded to two hydrogen atoms and two chlorine atoms, with each chlorine atom having three lone pairs.
C
A central carbon atom single-bonded to four chlorine atoms, with each chlorine atom having three lone pairs.
D
A central carbon atom double-bonded to one chlorine atom, single-bonded to two hydrogen atoms and one chlorine atom, with each chlorine atom having two lone pairs.
Verified step by step guidance
1
Identify the total number of valence electrons available for the molecule CH2Cl2. Carbon has 4 valence electrons, each hydrogen has 1, and each chlorine has 7. Calculate the sum: $4 + 2 \times 1 + 2 \times 7$.
Determine the central atom, which is typically the least electronegative element that can form multiple bonds. In CH2Cl2, carbon is the central atom.
Draw single bonds between the central carbon atom and each of the surrounding atoms (2 hydrogens and 2 chlorines). Each single bond represents 2 electrons.
Distribute the remaining valence electrons as lone pairs to satisfy the octet rule for the outer atoms (chlorines) and the central atom (carbon). Remember that hydrogen only needs 2 electrons to be stable.
Check that the total number of electrons used in bonds and lone pairs equals the total valence electrons calculated initially, and verify that carbon has a complete octet (8 electrons) and each chlorine has three lone pairs (6 electrons) plus the bonding pair.