At 900 K, the following reaction has 𝐾_𝑝 = 0.345: 2 SO₂(𝑔) + O₂(𝑔) ⇌ 2 SO₃(𝑔) In an equilibrium mixture the partial pressures of SO₂ and O₂ are 0.135 atm and 0.455 atm, respectively. What is the equilibrium partial pressure of SO₃ in the mixture?

Indicate whether each of the following statements about the reaction quotient Q is true or false: (b) If 𝑄_𝑐 < 𝐾_𝑐, the reaction needs to proceed to the right to reach equilibrium.

At 80°C, 𝐾_𝑐 = 1.87×10⁻³ for the reaction PH₃BCl₃(𝑠) ⇌ PH₃(𝑔) + BCl₃(𝑔) (a) Calculate the equilibrium concentrations of PH₃ and BCl₃ if a solid sample of PH₃BCl₃ is placed in a closed vessel at 80°C and decomposes until equilibrium is reached.

At 100°C, the equilibrium constant for the reaction COCl₂(𝑔) ⇌ CO(𝑔) + Cl₂(𝑔) has the value 𝐾_𝑐 = 2.19×10⁻¹⁰. Are the following mixtures of COCl₂, CO, and Cl₂ at 100°C at equilibrium? If not, indicate the direction that the reaction must proceed to achieve equilibrium.

(a) [COCl₂] = 2.00×10⁻³ M, [CO] = 3.3×10⁻⁶ M, [Cl₂] = 6.62×10⁻⁶ M

(b) [COCl₂] = 4.50×10⁻² M, [CO] = 1.1×10⁻⁷ M, [Cl₂] = 2.25×10⁻⁶ M

(c) [COCl₂] = 0.0100 M, [CO] = [Cl₂] = 1.48×10⁻⁶ M