Problem 50f
Determine the oxidation number for the indicated element in each of the following substances: f. Cr in BaCrO4.
Problem 51a
Which element is oxidized, and which is reduced in the following reactions? (a) N2(g) + 3 H2(g) → 2 NH3(g)
Problem 51c,d
Which element is oxidized, and which is reduced in the following reactions? (c) Cl2(aq) + 2 NaI(aq) → I2(aq) + 2 NaCl(aq) (d) PbS(s) + 4 H2O2(aq) → PbSO4(s) + 4 H2O(l)
Problem 52
Which of the following are redox reactions? For those that are, indicate which element is oxidized and which is reduced. For those that are not, indicate whether they are precipitation or neutralization reactions. (a) P4(s) + 10 HClO(aq) + 6 H2O(l) → 4 H3PO4(aq) + 10 HCl(aq) (b) Br2(l) + 2 K(s)→ 2 KBr(s) (c) CH3CH2OH(l) + 3 O2(g) → 3 H2O(l) + 2 CO2(g) (d) ZnCl2(aq) + 2 NaOH(aq) → Zn(OH)2(s) + 2 NaCl(aq)
Problem 53b
Write balanced net ionic equations for the reactions of b. aluminum with formic acid, HCOOH. Hint: These reactions produce a gas.
Problem 54b
Write balanced molecular and net ionic equations for the reactions of (b) dilute sulfuric acid with iron Hint: These reactions produce a gas.
Problem 55a,b
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (a) Iron metal is added to a solution of copper(II) nitrate (b) zinc metal is added to a solution of magnesium sulfate
Problem 55d
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (d) hydrogen gas is bubbled through an aqueous solution of nickel(II) chloride
Problem 55e
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (e) aluminum metal is added to a solution of cobalt(II) sulfate.
Problem 56a
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (a) Nickel metal is added to a solution of copper(II) nitrate
Problem 56d
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (d) chromium metal is immersed in an aqueous solution of cobalt(II) chloride
Problem 56e
Using the activity series (Table 4.5), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (e) hydrogen gas is bubbled through a solution of silver nitrate.
Problem 57b
The metal cadmium tends to form Cd2+ ions. The following observations are made: (i) When a strip of zinc metal is placed in CdCl2(aq), cadmium metal is deposited on the strip. (ii) When a strip of cadmium metal is placed in Ni(NO3)(aq), nickel metal is deposited on the strip. b. Is cadmium above or below zinc in the activity series?
Problem 58a
The following reactions (note that the arrows are pointing only one direction) can be used to prepare an activity series for the halogens:
Br2(aq) + 2 NaI(aq) → 2 NaBr(aq) + I2(aq)
Cl2(aq) + 2 NaBr(aq) → 2 NaCl(aq) + Br2(aq)
(a) Which elemental halogen would you predict is the most stable, upon mixing with other halides?
Problem 59a
(a) Is the number of moles of ions present in a solution an intensive or an extensive property?
Problem 59b
b. What is the difference between 0.50 mol HCl and 0.50 M HCl?
Problem 60b
You make 1.000 L of an aqueous solution that contains 35.0 g of sucrose (C12H22O11). (b) How many liters of water would you have to add to this solution to reduce the molarity you calculated in part (a) by a factor of two?
Problem 61c
(c) How many milliliters of a 6.00 M NaOH solution are needed to provide 0.350 mol of NaOH?
Problem 62b
(b) How many moles of KBr are present in 150 mL of a 0.112 M solution?
Problem 62c
(c) How many milliliters of 6.1 M HCl solution are needed to obtain 0.150 mol of HCl?
- The average adult human male has a total blood volume of 5.0 L. If the concentration of sodium ion in this average individual is 0.135 M, what is the mass of sodium ion circulating in the blood?
Problem 63
Problem 64
A person suffering from hyponatremia has a sodium ion concentration in the blood of 0.118 M and a total blood volume of 4.6 L. What mass of sodium chloride would need to be added to the blood to bring the sodium ion concentration up to 0.138 M, assuming no change in blood volume?
- The average adult male has a total blood volume of 5.0 L. After drinking a few beers, he has a BAC of 0.10 (see Exercise 4.65). What mass of alcohol is circulating in his blood?
Problem 66
Problem 67
(a) How many grams of ethanol, CH3CH2OH, should you dissolve in water to make 1.00 L of vodka (which is an aqueous solution that is 6.86 M ethanol)? (b) Using the density of ethanol (0.789 g/mL), calculate the volume of ethanol you need to make 1.00 L of vodka.
- In a sugar tolerance test, a patient needs to drink a glucose (C6H12O6) solution containing 100g glucose. Given that one cup is 350 mL, calculate the molarity of glucose in the glucose solution.
Problem 68
Problem 69a
(a) Which will have the highest concentration of potassium ions: 0.20 M KCl, 0.15 M K2CrO4, or 0.080 M K3PO4?
Problem 71a,b,c
Indicate the concentration of each ion or molecule present in the following solutions: (a) 0.35 M K3PO4 (b) 1.3×10−2 M MgSO4 (c) 0.0184 M CH3CH2OH
Problem 71d
Ignoring protolysis reactions, indicate the concentration of each ion or molecule present in the following solutions: (d) a mixture of 45.0 mL of 0.272 M NaCl and 65.0 mL of 0.0247 M (NH4)2CO3. Assume that the volumes are additive.
Problem 72a
Indicate the concentration of each ion present in the solution formed by mixing: (a) 42.0 mL of 0.170 M NaOH with 37.6 mL of 0.400 M NaOH.
Problem 72b
Indicate the concentration of each ion present in the solution formed by mixing: (b) 44.0 mL of 0.100 M Na2SO4 with 25.0 mL of 0.150 M KCl
Ch.4 - Reactions in Aqueous Solution
