NaCl has a lattice energy of -787 kJ/mol. Consider a hypothetical salt XY. X³⁺ has the same radius of Na⁺ and Y^3- has the same radius as Cl^-. Estimate the lattice energy of XY.

The cyanate ion (OCN^-) and the fulminate ion (CNO^-) share the same three atoms but have vastly different properties. The cyanate ion is stable, while the fulminate ion is unstable and forms explosive compounds. The resonance structures of the cyanate ion are explored in Example 9.8. Draw Lewis structures for the fulminate ion—including possible resonance forms— and use formal charge to explain why the fulminate ion is less stable (and therefore more reactive) than the cyanate ion.

Draw the Lewis structure for each organic compound from its condensed structural formula. b. CH₃OCH₃

Draw the Lewis structure for each organic compound from its condensed structural formula. c. CH₃COCH₃

Draw the Lewis structure for each organic compound from its condensed structural formula. e. CH₃CHO

Draw the Lewis structure for each organic compound from its condensed structural formula. a. C₂H₄ b. CH₃NH₂ c. HCHO d. CH₃CH₂OH e. HCOOH

Use Lewis structures to explain why Br₃^- and I₃^- are stable, while F₃^- is not.

Draw the Lewis structure for urea, H₂NCONH₂, one of the compounds responsible for the smell of urine. (The central carbon atom is bonded to both nitrogen atoms and to the oxygen atom.) Does urea contain polar bonds? Which bond in urea is most polar?

Some theories of aging suggest that free radicals cause certain diseases and perhaps aging in general. As you know from the Lewis model, such molecules are not chemically stable and will quickly react with other molecules. According to certain theories, free radicals may attack molecules within the cell, such as DNA, changing them and causing cancer or other diseases. Free radicals may also attack molecules on the surfaces of cells, making them appear foreign to the body's immune system. The immune system then attacks the cells and destroys them, weakening the body. Draw Lewis structures for each free radical implicated in this theory of aging. c. OH

Some theories of aging suggest that free radicals cause certain diseases and perhaps aging in general. As you know from the Lewis model, such molecules are not chemically stable and will quickly react with other molecules. According to certain theories, free radicals may attack molecules within the cell, such as DNA, changing them and causing cancer or other diseases. Free radicals may also attack molecules on the surfaces of cells, making them appear foreign to the body's immune system. The immune system then attacks the cells and destroys them, weakening the body. Draw Lewis structures for each free radical implicated in this theory of aging. d. CH₃OO (unpaired electron on terminal oxygen)

Free radicals are important in many environmentally significant reactions (see the Chemistry in the Environment box on free radicals in this chapter). For example, photochemical smog— smog that results from the action of sunlight on air pollutants— forms in part by these two steps:

The product of this reaction, ozone, is a pollutant in the lower atmosphere. (Upper atmospheric ozone is a natural part of the atmosphere that protects life on Earth from ultraviolet light.) Ozone is an eye and lung irritant and also accelerates the weathering of rubber products. Rewrite the given reactions using the Lewis structure of each reactant and product. Identify the free radicals.

If hydrogen were used as a fuel, it could be burned according to this reaction: H₂(g) + 1/2 O₂(g) → H₂O(g) Use average bond energies to calculate ΔH_rxn for this reaction.

If hydrogen were used as a fuel, it could be burned according to this reaction: H₂(g) + 1/2 O₂(g) → H₂O(g) Use average bond energies to calculate ΔH_rxn for the combustion of methane (CH₄).

If hydrogen were used as a fuel, it could be burned according to this reaction: H₂(g) + 1/2 O₂(g) → H₂O(g) Which fuel yields more energy per mole?

If hydrogen were used as a fuel, it could be burned according to this reaction: H₂(g) + 1/2 O₂(g) → H₂O(g) Which fuel yields more energy per gram?

Calculate ΔH_rxn for the combustion of octane (C₈H₁₈), a component of gasoline, by using average bond energies and then calculate it using enthalpies of formation from Appendix IIB. What is the percent difference between your results? Which result would you expect to be more accurate?

Draw the Lewis structure for each compound. a. Cl₂O₇ (no Cl–Cl bond)

Draw the Lewis structure for each compound. c. H₃AsO₄

The azide ion, N₃^-, is a symmetrical ion, all of whose contributing resonance structures have formal charges. Draw three important contributing structures for this ion.

Calculate the heat of atomization (see previous problem) of C₂H₃Cl, using the average bond energies in Table 9.3.

A compound composed of only carbon and hydrogen is 7.743% hydrogen by mass. Propose a Lewis structure for the compound.

A compound composed of only carbon and chlorine is 85.5% chlorine by mass. Propose a Lewis structure for the compound.