Problem 69
Determine the pH of an HNO2 solution of each concentration. In which cases can you not make the simplifying assumption that x is small? a. 0.500 M b. 0.100 M c. 0.0100 M
Problem 70
Determine the pH of an HF solution of each concentration. In which cases can you not make the simplifying assumption that x is small? (Ka for HF is 6.8×10–4.) a. 0.250 M b. 0.0500 M c. 0.0250 M
Problem 73
A 0.185 M solution of a weak acid (HA) has a pH of 2.95. Calculate the acid ionization constant (Ka) for the acid.
Problem 75
Determine the percent ionization of a 0.100 M HCN solution.
Problem 76
Determine the percent ionization of a 0.250 M solution of benzoic acid.
- What is the percent ionization of an acetic acid solution at the following concentrations? a. 1.00 M b. 0.500 M c. 0.100 M d. 0.0500 M
Problem 77
Problem 78a
Calculate the percent ionization of a formic acid solution having the given concentration. a. 1.00 M
Problem 78b
Calculate the percent ionization of a formic acid solution having the given concentration. b. 0.500 M
Problem 78c
Calculate the percent ionization of a formic acid solution having the given concentration. c. 0.100 M
Problem 78d
Calculate the percent ionization of a formic acid solution having the given concentration. d. 0.0500 M
Problem 79
A 0.148 M solution of a monoprotic acid has a percent ionization of 1.55%. Determine the acid ionization constant (Ka) for the acid.
- Find the pH and percent ionization of each HF solution. (Ka for HF is 6.8 * 10^-4.) a. 0.250 M HF b. 0.100 M HF c. 0.050 M HF.
Problem 81
- Find the pH and percent ionization of a 0.100 M solution of a weak monoprotic acid given the following Ka values: a. Ka = 1.0 * 10^-5, b. Ka = 1.0 * 10^-3, c. Ka = 1.0 * 10^-1.
Problem 82
Problem 83a
Find the pH of each mixture of acids. a. 0.115 M in HBr and 0.125 M in HCHO2
Problem 83b,c,d
Find the pH of each mixture of acids. b. 0.150 M in HNO2 and 0.085 M in HNO3 c. 0.185 M in HCHO2 and 0.225 M in HC2H3O2 d. 0.050 M in acetic acid and 0.050 M in hydrocyanic acid
Problem 84
Find the pH of each mixture of acids. a. 0.075 M in HNO3 and 0.175 M in HC7H5O2 b. 0.020 M in HBr and 0.015 M in HClO4 c. 0.095 M in HF and 0.225 M in HC6H5O d. 0.100 M in formic acid and 0.050 M in hypochlorous acid
Problem 85
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. a. 0.15 M NaOH b. 1.5×10–3 M Ca(OH)2 c. 4.8×10–4 M Sr(OH)2 d. 8.7×10–5 M KOH
Problem 86a
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. a. 8.77×10–3 M LiOH
Problem 86b
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. b. 0.0112 M Ba(OH)2
Problem 86c
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. c. 1.9×10–4 M KOH
Problem 86d
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. d. 5.0×10–4 M Ca(OH)2
Problem 87
Determine the pH of a solution that is 3.55% KOH by mass. Assume that the solution has density of 1.01 g/mL.
Problem 92a
Write equations showing how each weak base ionizes water to form OH–. Also write the corresponding expression for Kb. a. CO32–
Problem 92b
Write equations showing how each weak base ionizes water to form OH–. Also write the corresponding expression for Kb. b. C6H5NH2
Problem 92c
Write equations showing how each weak base ionizes water to form OH–. Also write the corresponding expression for Kb. c. C2H5NH2
Problem 93
Determine the [OH–], pH, and pOH of a 0.15 M ammonia solution.
Problem 95
Caffeine (C8H10N4O2) is a weak base with a pKb of 10.4. Calculate the pH of a solution containing a caffeine concentration of 455 mg/L.
Problem 96
Amphetamine (C9H13N) is a weak base with a pKb of 4.2. Calculate the pH of a solution containing an amphetamine concentration of 225 mg/L.
Problem 97
Morphine is a weak base. A 0.150 M solution of morphine has a pH of 10.7. What is Kb for morphine?
- A 0.135 M solution of a weak base has a pH of 11.23. Determine Kb for the base.
Problem 98
Ch.17 - Acids and Bases