Problem 83b,c,d
Find the pH of each mixture of acids. b. 0.150 M in HNO2 and 0.085 M in HNO3 c. 0.185 M in HCHO2 and 0.225 M in HC2H3O2 d. 0.050 M in acetic acid and 0.050 M in hydrocyanic acid
Problem 84
Find the pH of each mixture of acids. a. 0.075 M in HNO3 and 0.175 M in HC7H5O2 b. 0.020 M in HBr and 0.015 M in HClO4 c. 0.095 M in HF and 0.225 M in HC6H5O d. 0.100 M in formic acid and 0.050 M in hypochlorous acid
Problem 85
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. a. 0.15 M NaOH b. 1.5×10–3 M Ca(OH)2 c. 4.8×10–4 M Sr(OH)2 d. 8.7×10–5 M KOH
Problem 86a
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. a. 8.77×10–3 M LiOH
Problem 86b
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. b. 0.0112 M Ba(OH)2
Problem 86c
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. c. 1.9×10–4 M KOH
Problem 86d
For each strong base solution, determine [OH–], [H3O+], pH, and pOH. d. 5.0×10–4 M Ca(OH)2
Problem 87
Determine the pH of a solution that is 3.55% KOH by mass. Assume that the solution has density of 1.01 g/mL.
Problem 92a
Write equations showing how each weak base ionizes water to form OH–. Also write the corresponding expression for Kb. a. CO32–
Problem 92b
Write equations showing how each weak base ionizes water to form OH–. Also write the corresponding expression for Kb. b. C6H5NH2
Problem 92c
Write equations showing how each weak base ionizes water to form OH–. Also write the corresponding expression for Kb. c. C2H5NH2
Problem 93
Determine the [OH–], pH, and pOH of a 0.15 M ammonia solution.
Problem 95
Caffeine (C8H10N4O2) is a weak base with a pKb of 10.4. Calculate the pH of a solution containing a caffeine concentration of 455 mg/L.
Problem 96
Amphetamine (C9H13N) is a weak base with a pKb of 4.2. Calculate the pH of a solution containing an amphetamine concentration of 225 mg/L.
Problem 97
Morphine is a weak base. A 0.150 M solution of morphine has a pH of 10.7. What is Kb for morphine?
- A 0.135 M solution of a weak base has a pH of 11.23. Determine Kb for the base.
Problem 98
Problem 99
Determine if each anion acts as a weak base in solution. For those anions that are basic, write an equation that shows how the anion acts as a base. a. Br– b. ClO– c. CN– d. Cl–
Problem 100c
Determine whether each anion is basic or neutral. For those anions that are basic, write an equation that shows how the anion acts as a base. c. NO3–
Problem 101
Determine the [OH–] and pH of a solution that is 0.140 M in F–.
- Determine the [OH-] and pH of a solution that is 0.250 M in HCO3⁻.
Problem 102
Problem 103a
Determine whether each cation is acidic or pH-neutral. For those cations that are acidic, write an equation that shows how the cation acts as an acid. a. NH4+
Problem 103b
Determine whether each cation is acidic or pH-neutral. For those cations that are acidic, write an equation that shows how the cation acts as an acid. b. Na+
Problem 103c
Determine whether each cation is acidic or pH-neutral. For those cations that are acidic, write an equation that shows how the cation acts as an acid. c. Co3+
Problem 103d
Determine whether each cation is acidic or pH-neutral. For those cations that are acidic, write an equation that shows how the cation acts as an acid. d. CH2NH3+
Problem 104a,b,c
Determine whether each cation is acidic or pH-neutral. For each cation that is acidic, write an equation that shows how the cation acts as an acid. a. Sr2+ b. Mn3+ c. C5H5NH+
Problem 104d
Determine whether each cation is acidic or pH-neutral. For each cation that is acidic, write an equation that shows how the cation acts as an acid. d. Li+
Problem 105e
Determine if each salt will form a solution that is acidic, basic, or pH-neutral. e. C6H5NH3NO2
Problem 106a
Determine if each salt will form a solution that is acidic, basic, or pH-neutral. a. Al(NO3)3
Problem 107
Arrange the solutions in order of increasing acidity. NaCl, NH4Cl, NaHCO3, NH4ClO2, NaOH
- Arrange the solutions in order of increasing basicity: CH3NH3Br, KOH, KBr, KCN, C5H5NHNO2.
Problem 108
Ch.17 - Acids and Bases