17. Amines

Write the structures of the following compounds:

a. Butyldiethylammonium bromide

Write the structure of benzylamine hydrochloride in two different ways, and name the hydrochloride as an ammonium salt.

Give names or structures for the following ammonium salts. Indicate whether each is the ammonium salt of a primary, secondary, or tertiary amine.

a.

Give names or structures for the following ammonium salts. Indicate whether each is the ammonium salt of a primary, secondary, or tertiary amine.

a.

Give names or structures for the following ammonium salts. Indicate whether each is the ammonium salt of a primary, secondary, or tertiary amine.

c. N-Butyl-N-isopropylhexylammonium chloride

Draw structure for N,N-diethyl-2-hexanaminium.

Draw structure for propylammonium ion.

Provide the IUPAC name for the following ammonium salt.

Which of the following represents m-bromo-N-ethyl-N-isopropylbenzenaminium?

Draw the condensed structural or line-angle formula if cyclic, for each of the following:

d. ethylmethylammonium bromide

Novocain, a local anesthetic, is the ammonium salt of procaine.

a. Draw the condensed structural formula for the ammonium salt (procaine hydrochloride) formed when procaine reacts with HCl. (Hint: The tertiary amine reacts with HCl.)

Lidocaine (xylocaine) is used as a local anesthetic and cardiac depressant.

a. Draw the condensed structural formula for the ammonium salt formed when lidocaine reacts with HCl.