The semiconductor industry manufactures integrated circuits in large vacuum chambers where the pressure is 1.0×10-10 mm of Hg. At T=20°C, how many molecules are in a cylindrical chamber 40 cm in diameter and 30 cm tall?
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21. Kinetic Theory of Ideal Gases
The Ideal Gas Law
Problem 68a
Textbook Question
In Problems and you are given the equation(s) used to solve a problem. For each of these, you are to write a realistic problem for which this is the correct equation(s).

1
Step 1: Recognize that the given equation is a form of the combined gas law, which relates the pressure, volume, and temperature of a gas. The combined gas law is expressed as: \( \frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} \). In this case, the volume \( V \) is constant, so it simplifies to \( \frac{P_1}{T_1} = \frac{P_2}{T_2} \).
Step 2: Analyze the given equation: \( (T_2 + 273) \, \text{K} = \frac{200 \, \text{kPa}}{500 \, \text{kPa}} \times 1 \times (400 + 273) \text{K} \). This equation suggests that the problem involves a gas undergoing a change in pressure and temperature, with the volume held constant.
Step 3: Write a realistic problem based on the equation. For example: 'A gas is initially at a pressure of 500 kPa and a temperature of 400°C. The gas is then cooled while maintaining a constant volume, and its pressure decreases to 200 kPa. What is the final temperature of the gas in degrees Celsius?'
Step 4: Explain how the equation is used to solve the problem. The equation \( \frac{P_1}{T_1} = \frac{P_2}{T_2} \) is rearranged to solve for \( T_2 \): \( T_2 = \frac{P_2}{P_1} \times T_1 \). Here, \( T_1 \) is converted to Kelvin by adding 273 to the initial temperature in Celsius, and \( T_2 \) is converted back to Celsius after solving.
Step 5: Substitute the known values into the equation: \( T_2 + 273 = \frac{200}{500} \times (400 + 273) \). Simplify the expression to find \( T_2 \) in Kelvin, then subtract 273 to convert it to Celsius. This provides the final temperature of the gas after the pressure change.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Ideal Gas Law
The Ideal Gas Law is a fundamental equation in thermodynamics that relates the pressure, volume, temperature, and number of moles of an ideal gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. Understanding this law is crucial for solving problems involving gas behavior under varying conditions.
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Temperature Conversion
Temperature conversion is the process of changing a temperature value from one scale to another, such as Celsius to Kelvin. The Kelvin scale is an absolute temperature scale where 0 K is absolute zero, and it is calculated by adding 273.15 to the Celsius temperature. This conversion is essential in thermodynamic equations to ensure that temperature values are in the correct units for calculations.
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Unit Conversions
Pressure Units
Pressure is defined as the force exerted per unit area and is commonly measured in units such as pascals (Pa), kilopascals (kPa), and atmospheres (atm). In the context of the given equation, understanding how to convert and compare different pressure units is vital for solving problems related to gas laws and thermodynamic processes. The relationship between pressure and temperature is key in determining the behavior of gases.
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